Do they follow a curriculum (sp?)? If so, how intense is it? (Personally, we prefer a heavy emphasis on learning through structured play instead of table work, etc, but that is just our preference).
Do they require potty training?
Do they provide lunch? Snacks?
what is a typical day like?
What are the safety precautions (you can usually see this. Can people just walk right in? Is there more than one gate to an outdoor play area? Is this staffed?)
student to teacher ratio was up there for me, and how they deal with discipline, teachers' availability to speak with parents - those were some i asked...